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material safety data sheet  
Broadsword

  1. Identification
  2. Composition/Information on Ingredients
  3. Hazards Identification
  4. First Aid Measures
  5. Fire Fighting Measures
  6. Accidental Release Measures
  7. Handling and Storage
  8. Exposure Control/Personal Protection
  9. Physical and Chemical Properties
  10. Stability and Reactivity
  11. Toxicological Information
  12. Ecological Information
  13. Disposal Consideration
  14. Transport
  15. Regulatory Information
  16. Other Information

1. identification

Preparation:

Broadsword

Supplier:

Nomix Enviro Ltd, Portland Building, Portland Street, Staple Hill, Bristol BS16 4PS
T: 0117 957 4574; F: 0117 956 3461

Chemical Emergency Agency Service 24 hour: 01865 407 333
2. composition/information on ingredients

Composition:

 (2,4-dichlorophenoxy) acetic acid, 2-ethylhexyl ester (2,4-D 2EH) CAS NO. 1928-43-4; 200 g/l (19.34 wt%)
                                               
3,6-dichloro-o-anisic acid (dicamba); CAS NO. 1918-00-9; 85 g/l (8.22 wt%)

3,5,6-trichloro-2-pyridyloxyacetic acid, butoxyethyl ester (triclopyr, butotyl); CAS NO. 64470-88-8; 65 g/l (6.29 wt%)

MAPP Number:

09140
3. hazards identification

Human Health Hazards      
Harmful by inhalation, in contact with skin and if swallowed.

Environmental Hazards       
Toxic to aquatic organisms.

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4. first aid measures
Eye contact                
Immediately wash out with plenty of water with the eyelid held wide open.  Immediately
consult a doctor.

Skin Contact                          
Immediately wash off with plenty of water and soap.

Ingestion
Keep victim at rest in half upright position.  Wash out mouth with plenty of water.  If victim is unconscious, place in lateral recovery position.  Immediately get medical attention.  Decision on inducing vomiting should be made by attending physician.  Aspiration during ingestion or vomiting can result in serious lung damage.

Inhalation                  
Immediately remove victim to fresh air.  Keep victim at rest in half upright position.  If victim is unconscious, place in lateral recovery position.  If not breathing use artificial respiration.  Immediately get medical attention.

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5. fire fighting measures

Extinguishing Media 
Dry chemical, water spray, foam, carbon dioxide

Special Fire Fighting Procedures
Save fire control water for later disposal.

Unusual Fire/Explosion Hazards
Solvent naphtha (petroleum) light aroma.  May form flammable explosive mixtures with air.  Electrostatic charges may be generated during handling.

Hazardous Thermal Decomposition Products
Toxic and irritating fumes, toxic flammable and explosive gas.

Protection of Fire Fighters
Chemical resistant clothing.  Self contained breathing apparatus with full face shield.

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6. accidental release measures

Personal Precautions
Rubber gloves.  Filter mask with full face shield.  Chemical resistant clothing.

Environmental Precautions  
Prevent all discharge into the environment.  Inform relevant authorities if the product has caused environmental pollution (surface water, soil or air).

Methods for Cleaning up      
Absorb into earth or sand or another inert material.  Disposal according to the local legislation.

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7. handling and storage

Handling                    
Spatial air extraction essential. Do not breath vapour or spray.  Avoid contact with skin and eyes.  Fire hazard.  Conditions to avoid: heat, sources of ignition.

Storage                      
Keep out of the reach of children.  Keep away from food, drink and animal feedstuffs.  Keep container in a well-ventilated place.  Keep only in original container.  Keep container tightly closed.  Store in fireproof location.

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8. exposure control/personal protection

Occupational Exposure      
No occupational exposure limits have been established – United Kingdom

Engineering measures        
Spatial air extraction essential, do not breath vapour or spray.  Avoid contact with and eyes.  Fire hazard.  Conditions to avoid heat, sources of ignition.

Hygiene Measures  
After handling wash hands thoroughly with soap and water.  When using do not eat or
drink.  Wear clean work clothing regularly.  Take off contaminated clothing immediately.

Respiratory System 
Filter mask with full face shield (gas/vapour filter (A) )

Body and Hands   
Chemical resistant clothing and gloves.

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9. physical and chemical properties

Physical State: Low viscosity liquid
Appearance/Colour: Brown
Odour: Organic Solvents
pH: 2.67 (1% solution in water)
Flash Point: 41°C
Solubility in Water: Miscible
Specific Gravity: 1.02 – 1.05

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10. stability and reactivity

Stability: Shelf life – 2 years
Materials to Avoid: Strong acids, strong bases, oxidising agents.
Hazardous Decomposition Products: Toxic and irritating fumes.

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11. toxicological info

No data available

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12. ecological information

No data available

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13. disposal considerations

Spillage and Disposal
Dispose of this material and its container via specialist waste collection facility.  Dispose according to local legislation.    

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14. transport

UN Number : 2995
Proper Shipping Name: Organochlorine pesticide, liquid, toxic
(2,4-D 20%/naphtha solvent solution)
ADR/RID Class: 6.1
ADR/RID Item number: 72b
Packing Group: II
Haz Identification: 63
ADR/RID label: Toxic + flammable + marine pollutant

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15. regulatory information

This product is covered by the Control of Pesticides Regulations (1986) and has been labelled in accordance with those regulations.  The Control of Substances Hazardous to Health Regulations 1998 (COSHH) may apply to the use of this product.

Hazard Symbol: Xn, Harmful

R Phrases:
R10 Flammable
R20/21/22  Harmful by inhalation, in contact with skin or if swallowed
R43 May cause sensitisation by skin contact
R51/53  Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
                                               
Safety Phrases :   
S2  Keep out of reach of children
S13 Keep away from food, drink or animal feeding stuffs. 
S16 Keep away from sources of ignition – no smoking
S20/21 When using do not eat, drink or smoke.
S36/37/39 Wear  suitable protective clothing, gloves, and eye/face protection.
S38 In case of insufficient ventilation, wear suitable respiratory equipment

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16. other information

The information contained within this Material Safety Data Sheet does not constitute the users own assessment of workplace risk as required by other national health and safety legislation such as the Health and Safety at Work Act (1974) and the Control of Substances Hazardous to Health Regulations(1988).

Read the label before you buy: Use pesticides safely.

Date of MSDS Review : 22/07/04

Supersedes MSDS Dated: 23/05/00

The information in this data sheet is to the best of our knowledge true and accurate, but all instructions, recommendations and suggestions are made without guarantee. Since the conditions of use are beyond their control, Nomix Enviro and its subsidiaries disclaim any liability for the loss or damage suffered from use of this information. Furthermore no liability is accepted if use of any product in accordance with these instructions, recommendations and suggestions infringes any patent.

© Nomix Enviro Limited 2004

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